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81.
[reaction: see text] Terminal acetylenes containing hydroxy and carboxylic acid groups were subjected to Sonogashira coupling with 4-bromo-2,6-bis[(R)-4-phenyloxazolin-2-yl]pyridine and the resulting pybox derivatives were immobilized on Tentagel resins. Ytterbium(III) chloride complexes of the polymeric ligands catalyzed the addition of trimethylsilyl cyanide to benzaldehyde with 80-81% ee. The ligands were reused more than 30 times without any loss in selectivity or activity, and the metal complexes could be recovered and reused at least four times, although with slightly decreasing activity. 相似文献
82.
Anurag Gupta Bruce C. Kim Eugene Edwards Christina Brantley Paul Ruffin 《Applied Physics A: Materials Science & Processing》2012,107(3):709-714
In this work, we synthesize hierarchical ZnO nanowires in a customized atmospheric CVD furnace and investigate their surface modification behavior for prospective nitroaromatic sensing applications. The morphology and crystal structure of pristine nanowires are characterized through FE-SEM, TEM, X-ray diffraction and EDAX studies. Photoluminescence behavior of pristine nanowires is also reported. Surface modification behavior of synthesized nanowires on a ZnO–oleic acid system is studied by utilizing Raman and FT-IR spectroscopy. Based on these findings, 1-pyrenebutyric acid (PBA) has been identified as an appropriate fluorescent receptor for sensing p-nitrophenol. Fluorescence quenching experiments on a PBA–p-nitrophenol system are reported and a detection limit of up to 28 ppb is envisaged for PBA-grafted ZnO nanowire-based optical sensor. 相似文献
83.
Dr. Carlo Fasting Prof. Christoph A. Schalley Dr. Marcus Weber Prof. Oliver Seitz Prof. Stefan Hecht Prof. Beate Koksch Dr. Jens Dernedde Prof. Christina Graf Prof. Ernst‐Walter Knapp Prof. Rainer Haag 《Angewandte Chemie (International ed. in English)》2012,51(42):10472-10498
Multivalent interactions can be applied universally for a targeted strengthening of an interaction between different interfaces or molecules. The binding partners form cooperative, multiple receptor–ligand interactions that are based on individually weak, noncovalent bonds and are thus generally reversible. Hence, multi‐ and polyvalent interactions play a decisive role in biological systems for recognition, adhesion, and signal processes. The scientific and practical realization of this principle will be demonstrated by the development of simple artificial and theoretical models, from natural systems to functional, application‐oriented systems. In a systematic review of scaffold architectures, the underlying effects and control options will be demonstrated, and suggestions will be given for designing effective multivalent binding systems, as well as for polyvalent therapeutics. 相似文献
84.
85.
In this paper we continue the study of paired-domination in graphs introduced by Haynes and Slater (Networks 32 (1998), 199–206). A paired-dominating set of a graph G with no isolated vertex is a dominating set of vertices whose induced subgraph has a perfect matching. The paired-domination
number of G, denoted by γ
pr(G), is the minimum cardinality of a paired-dominating set of G. The graph G is paired-domination vertex critical if for every vertex v of G that is not adjacent to a vertex of degree one, γ
pr(G − v) < γ
pr(G). We characterize the connected graphs with minimum degree one that are paired-domination vertex critical and we obtain sharp
bounds on their maximum diameter. We provide an example which shows that the maximum diameter of a paired-domination vertex
critical graph is at least 3/2 (γ
pr(G) − 2). For γ
pr(G) ⩽ 8, we show that this lower bound is precisely the maximum diameter of a paired-domination vertex critical graph.
The first author was supported in part by the South African National Research Foundation and the University of KwaZulu-Natal,
the second author was supported by the Natural Sciences and Engineering Research Council of Canada. 相似文献
86.
Mitra Shojania Feizabadi Christina Volk Sarah Hirschbeck 《Applied Mathematics Letters》2009,22(8):1205-1209
By combining the total cell evolution curve and a two-compartment model interacting with dynamic anti-cancer agents, the evolution of subpopulations has been analytically obtained and investigated in this work. 相似文献
87.
Christina H. Chen Ashil K. Higgins Reinhold M. Strnat 《Journal of magnetism and magnetic materials》2008
The effect of specimen geometry on magnetization distortion in closed-circuit measurements is reported in this letter. The degree of the distortion increases as the ratio of length to diameter (L/D) of specimen decreases, and the distortion can reduce the magnetization values as much as 42% when the applied magnetic field is 24 kOe and the L/D is 0.28. The type of magnetic material also affects the distortion. Although the phenomenon seems to be similar to the “image effect” that occurs in open-circuit measurements, reports of this effect in closed-circuit measurements have not been found in the literature. Further research effort, including 3D computer modeling, for understanding this magnetic phenomenon is underway and will be reported later. 相似文献
88.
Iovka Dragieva Christina Deleva Mladen Mladenov Ivania Markova-Deneva 《Monatshefte für Chemie / Chemical Monthly》2002,82(1):807-814
Different structures of the interglobular space or voids between self-organized nanoparticles lead to differences in the measurable magnetic properties of single-domain particle chains of similar composition, grain size, and amorphous structure of the single globules. The volumes and radii of nanoparticles obtained by application of a magnetic field (3 to 15 nm) are larger than those determined without application of a magnetic field during the borohydride reduction process. Two types of hydrogen containing nanotubes with diameters of up to 2 (small-size containers) and 5 nm (large-size containers) are produced using as a driving force the domain wall formation energy between ferromagnetic nanoparticles with quantum size effected dimensions prepared by this reduction method at room temperature and ambient atmosphere. Nanoscale hydrogen containers can be used instead of MeH nanoparticle electrodes as perfect energy charge transfer media of high efficiency (close to 100%) using Li ion electrolytes. No influence on the electrode temperature and no participation of OH− and H2O in the main charge/discharge transfer reactions were observed. 相似文献
89.
Penna Thereza Christina Vessoni Moraes Dante Augusto 《Applied biochemistry and biotechnology》2002,98(1-9):775-789
Applied Biochemistry and Biotechnology - The production of nisin by batch culture of Lactococcus lactis ATCC 11454 in MRS broth (pH 6.5), as treated in 30 assays, that were set up by a fractional... 相似文献
90.
Asawin Likhitsup Anbanandam Parthiban Christina L. L. Chai 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):102-116
A simple, one‐step procedure has been developed for the preparation of bifunctional initiators capable of polymerizing monomers suitable for atom‐transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP). These bifunctional initiators were employed for making narrow disperse poly(styrene) macroinitiators, which were subsequently used for the ROP of various lactides to yield poly(styrene‐block‐lactide) copolymers. Thermogravimetric analysis (TGA) of these block copolymers are interesting in that it shows a two‐step degradation curve with the first step corresponding to the degradation of poly(lactide) segment and the second step associated with the poly(styrene) segment of the block copolymer. This nature of the block copolymer makes it possible to estimate the block copolymer content by TGA in addition to the 1H NMR spectroscopic analysis. Thus, this study for the first time highlights the possibility of making porous materials by thermal means which are otherwise obtained by base hydrolysis. The bifunctional initiators were prepared by the esterification of 3‐hydroxy, 4‐hydroxy, and 3,5‐dihydroxy benzyl alcohols with α‐bromoisobutyryl bromide and 2‐bromobutyryl bromide. A mixture of products was obtained, which were purified by column chromatography. The esterified benzyl alcohols were employed in the polymerization of styrene under copper (Cu)‐catalyzed ATRP conditions to yield macroinitiators with low polydispersity. These macroinitiators were subsequently used in the ROP of L ‐, DL ‐, and mixture of lactides. The formation of block copolymers was confirmed by gel permeation chromatography (GPC), spectroscopic and thermal characterizations. The molecular weight of the block copolymers was always higher than the macroinitiator, and the GPC chromatogram was symmetrical indicating the uniform initiation of ROP by the macroinitiators. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 102–116, 2008 相似文献